跳转至内容
Merck
CN

主要文件

查看所有文档

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

powder

登录 查看组织和合同定价。

选择尺寸

变更视图

关于此项目

经验公式（希尔记法）:
C44H34F20IrN4P
化学文摘社编号:
2222402-20-0
分子量:
1221.93
MDL number:
MFCD32851671
UNSPSC Code:
12352101
NACRES:
NA.22
技术服务
需要帮助？我们经验丰富的科学家团队随时乐意为您服务。
让我们为您提供帮助

产品名称

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6,

form

powder

Quality Level

100

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

mp

378 °C

SMILES string

[Ir+].FC(F)(F)c5cnc(cc5)c6c(cc(cc6)C(F)(F)F)F.FC(F)(F)c3cnc(cc3)c4c(cc(cc4)C(F)(F)F)F.F[P-](F)(F)(F)(F)F.n1c(cc(cc1)C(C)(C)C)c2nccc(c2)C(C)(C)C

InChI key

HNVAXJZTSVKZHB-UHFFFAOYSA-N

Application

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

新产品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCM1271

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Jack Twilton et al.
Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation

全球贸易项目编号

货号GTIN
912948-500MG04061841994879
912948-50MG04061841994886