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908886

N-Cyano-4-methoxy-picolinimidamide

Name: <I>N</I>-Cyano-4-methoxy-picolinimidamide
Brand: ALDRICH

≥95%, powder or crystals

别名:

Weix ligand

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关于此项目

经验公式（希尔记法）:

C₈H₈N₄O

化学文摘社编号:

1988789-96-3

分子量:

176.18

MDL number:

MFCD32173815

UNSPSC Code:

12352111

NACRES:

NA.22

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属性

产品名称

N-Cyano-4-methoxy-picolinimidamide, ≥95%

assay

≥95%

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

220-225 °C

SMILES string

N(C(=N)c1nccc(c1)OC)C#N

InChI

1S/C8H8N4O/c1-13-6-2-3-11-7(4-6)8(10)12-5-9/h2-4H,1H3,(H2,10,12)

InChI key

LEWHOCRDELQPCV-UHFFFAOYSA-N

说明

Application

This pyridyl carboxamidine ligand has been demonstrated by Daniel Weix′s lab to enable nickel-catalyzed cross-coupling of diverse basic nitrogen heterocycles with primary and secondary alkyl halides.

Other Notes

New ligands for nickel catalysis from diverse pharmaceutical heterocycle libraries

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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New ligands for nickel catalysis from diverse pharmaceutical heterocycle libraries.

Eric C Hansen et al.

Nature chemistry, 8(12), 1126-1130 (2016-11-23)

Ligands are essential for controlling the reactivity and selectivity of reactions catalysed by transition metals. Access to large phosphine ligand libraries has become an essential tool for the application of metal-catalysed reactions industrially, but these existing libraries are not well