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Merck
CN

928283

RuPhos Pd G3 ChemBeads

solid

别名:

Adam’s (2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, RuPhos-G3-Palladacycle, RuPhos-Pd-G3

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关于此项目

经验公式(希尔记法):
C43H56NO5PPdS
化学文摘社编号:
分子量:
836.37
UNSPSC Code:
12352101
NACRES:
NA.82
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产品名称

RuPhos Pd G3 ChemBeads,

Quality Level

product line

ChemBeads

form

solid

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

extent of labeling

~5 wt. % loading of catalyst

SMILES string

NC1=C(C2=C([Pd](OS(=O)(C)=O)P(C3CCCCC3)(C4CCCCC4)C5=CC=CC=C5C6=C(C=CC=C6OC(C)C)OC(C)C)C=CC=C2)C=CC=C1

InChI key

OEVHKTCNQBOMNB-UHFFFAOYSA-N

General description

RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

For larger scale uses, product also available in powdered form (763403)

Application

RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:

Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers. Suzuki-Miyaura-cross-coupling of aminothiophenes.

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products


pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

Carc. 1B Inhalation

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

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商品

ChemBeads, catalyst-coated glass beads, dispense solid chemical reagents for nanomole-scale high-throughput reaction screening.





全球贸易项目编号

货号GTIN
928283-1G04065268510605