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Merck
CN

928305

cataCXium® A Pd G3 ChemBeads

solid

别名:

Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3

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关于此项目

经验公式(希尔记法):
C37H52NO3PPdS
化学文摘社编号:
分子量:
728.27
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.82
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产品名称

cataCXium® A Pd G3 ChemBeads,

Quality Level

product line

ChemBeads

form

solid

composition

~ 4 wt.% loading of catalyst

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

SMILES string

[Pd+2].P(C76CC8CC(C7)CC(C6)C8)(C43CC5CC(C4)CC(C3)C5)CCCC.[S](=O)(=O)([O-])C.Nc1c(cccc1)c2[c-]cccc2

InChI key

QFHMWCPYABRFMY-UHFFFAOYSA-M

Application

cataCXium® A Pd G3 is a Buchwald third generation precatalyst that can be used in:

  • Direct ortho-arylation of pyridinecarboxylic acids.
  • Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
  • Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
  • Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (761435)

Legal Information

cataCXium is a registered trademark of Umicore AG & Co. KG


pictograms

Health hazard

signalword

Danger

hcodes

Hazard Classifications

Carc. 1B Inhalation

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

ChemBeads, catalyst-coated glass beads, dispense solid chemical reagents for nanomole-scale high-throughput reaction screening.





全球贸易项目编号

货号GTIN
928305-1G04065268466896