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Merck
CN

296309

1,4-二氧六环

anhydrous, 99.8%, contains <=25 ppm BHT as stabilizer

别名:

二恶烷, 四氢呋喃

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关于此项目

经验公式(希尔记法):
C4H8O2
化学文摘社编号:
分子量:
88.11
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-661-8
Beilstein/REAXYS Number:
102551
MDL number:
Assay:
99.8%
Grade:
anhydrous
Bp:
100-102 °C (lit.)
Vapor pressure:
27 mmHg ( 20 °C), 40 mmHg ( 25 °C)
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grade

anhydrous

Quality Level

vapor density

3 (vs air)

vapor pressure

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

assay

99.8%

form

liquid

autoignition temp.

356 °F

expl. lim.

22 %

impurities

<0.003% water, <0.005% water (100 mL pkg)

evapn. residue

≤0.005%

refractive index

n20/D 1.422 (lit.)

pH

6.0-8 (20 °C, 500 g/L)

bp

100-102 °C (lit.)

mp

10-12 °C (lit.)

density

1.034 g/mL at 25 °C (lit.)

SMILES string

C1COCCO1

InChI

1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2

InChI key

RYHBNJHYFVUHQT-UHFFFAOYSA-N

Application

1,4-二恶烷可与芳基硼酸进行镍催化的氧化芳基化,形成α-芳基醚。
它可作为溶剂用于合成:
  • (氯甲基)二甲基苯基硅烷,来自氯(氯甲基)二甲基硅烷与苯基溴化镁通过锌催化的取代反应。
  • N(2,2,2-三氟-1-羟乙基)-乙酰胺,来自于2,2,2-三氟-1-甲氧基乙醇和乙酰胺。

Packaging

Other Notes

货号296309-4X2L的产品即将停产。请订购296309-2L单瓶装,因为其物理参数与上述产品本质相同。


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Danger

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

如果物质相互溶解形成均匀的溶液,就可以说它们相互混溶。收藏或下载我们的常见实验室溶剂混溶性表。

Substances are said to be miscible in one another if they dissolve to form a uniform solution. Bookmark or download our miscibility table for common lab solvents.

Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.

查看所有文章

Synthesis of tetraorganosilanes: (chloromethyl)dimethylphenylsilane
Murakami K, et al.
Organic Syntheses, 87, 178-178 (2010)
A xanthate-transfer approach to ?-trifluoromethylamines
Gagosz F and Zard FS
Organic Syntheses, 84, 32-32 (2007)
Raquel Palao-Suay et al.
Macromolecular bioscience, 16(12), 1824-1837 (2016-10-16)
Well-structured amphiphilic copolymers are necessary to obtain self-assembled nanoparticles (NPs) based on synthetic polymers. Highly homogeneous and monodispersed macromolecules obtained by controlled polymerization have successfully been used for this purpose. However, disaggregation of the organized macromolecules is desired when a



全球贸易项目编号

货号GTIN
296309-100ML04061837532733
296309-200L04061838161437
296309-200L-KL04061838151940
296309-6X1L04061826649930
296309-12X100ML04061826649459
296309-18L04061838161420
296309-1L04061837532757
296309-250ML04061837536885
296309-2L04061837532764