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Merck
CN

757136

Lithium bis(oxalato)borate

greener alternative

Synonym(s):

LiBOB, Lithium bis(ethanedioato)borate, Lithium bis(oxalate)borate

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About This Item

Linear Formula:
LiB(C2O4)2
CAS Number:
Molecular Weight:
193.79
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
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form

powder or crystals

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

[Li+].O=C1O[B-]2(OC1=O)OC(=O)C(=O)O2

InChI

1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1

InChI key

NVQAYVUCVASGDK-UHFFFAOYSA-N

General description

Lithium bis(oxalato)borate (LiBOB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

LiBOB is a thermally stable electrolyte that can be used to protect graphite-based anode materials in lithium-ion batteries. It shows good electrochemical performance with a discharge capacity retention of ~ 83%.
LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.


pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1A

Storage Class

13 - Non Combustible Solids

wgk

WGK 1



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Shoichi Matsuda et al.
Scientific reports, 9(1), 6211-6211 (2019-04-19)
Data-driven material discovery has recently become popular in the field of next-generation secondary batteries. However, it is important to obtain large, high quality data sets to apply data-driven methods such as evolutionary algorithms or Bayesian optimization. Combinatorial high-throughput techniques are
Jenny Strehlau et al.
Analytical and bioanalytical chemistry, 409(26), 6123-6131 (2017-08-05)
A novel method based on liquid-liquid extraction with subsequent gas chromatography separation and mass spectrometric detection (GC-MS) for the quantification of organic carbonates in cell culture materials is presented. Method parameters including the choice of extraction solvent, of extraction method
Lithium bis (oxalato) borate stabilizes graphite anode in propylene carbonate
Xu K, et al.
Electrochemical and Solid-State Letters, 5(11), A259-A259 (2002)



Global Trade Item Number

SKUGTIN
757136-25G04061838351906