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901219

VPhos Pd G3

Name: VPhos Pd G3
Brand: ALDRICH

95%, powder or crystals

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About This Item

Empirical Formula (Hill Notation):

C₄₆H₆₂NO₄PPdS

Molecular Weight:

862.45

UNSPSC Code:

12161600

NACRES:

NA.22

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Properties

Product Name

VPhos Pd G3, 95%

Quality Level

100

product line

Buchwald precatalyst Generation 3

assay

95%

form

powder or crystals

feature

generation 3

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

functional group

phosphine

Description

Application

Buchwald palladacycle precatalyst with new biaryl(dialkyl)phosphine ligand, VPhos, has an improved activity profile for the reductive coupling of non-aromatic heterocyclic alkyl bromides. Its combined use with a surfactant system of octanoic acid/sodium octanoate enables Negishi coupling and access to diverse C(sp³)–C(sp²) cross-coupled products.

Other Notes

An Improved System for the Aqueous Lipshutz–Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Global Trade Item Number

SKU	GTIN
901219-1G	04061835508792
901219-250MG	04061835505333