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905518

Ir(dFFppy)2(dtbbpy)PF6

solid

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About This Item

Empirical Formula (Hill Notation):
C40H34F12IrN4P
CAS Number:
2042201-18-1
Molecular Weight:
1021.90
MDL number:
MFCD31807347
UNSPSC Code:
12161600
NACRES:
NA.22
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Product Name

Ir(dFFppy)2(dtbbpy)PF6,

form

solid

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

465 nm

SMILES string

FC1=C(C2=NC=C(F)C=C2)C([Ir]3([N]4=CC=C(C(C)(C)C)C=C4C5=CC(C(C)(C)C)=CC=[N]53)C6=CC(F)=CC(F)=C6C7=CC=C(F)C=N7)=CC(F)=C1.FP(F)(F)(F)(F)F

Application

Ir(dFFppy)2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Metallaphotoredox-catalysed sp3–sp3cross-coupling of carboxylic acids with alkyl halides

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Craig P Johnston et al.
Nature, 536(7616), 322-325 (2016-08-19)
In the past 50 years, cross-coupling reactions mediated by transition metals have changed the way in which complex organic molecules are synthesized. The predictable and chemoselective nature of these transformations has led to their widespread adoption across many areas of