912948
Ir[FCF3(CF3)ppy]2(dtbbpy)PF6
powder
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About This Item
Empirical Formula (Hill Notation):
C44H34F20IrN4P
CAS Number:
Molecular Weight:
1221.93
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
Product Name
Ir[FCF3(CF3)ppy]2(dtbbpy)PF6,
form
powder
Quality Level
reaction suitability
reaction type: Photocatalysis, reagent type: catalyst
mp
378 °C
SMILES string
[Ir+].FC(F)(F)c5cnc(cc5)c6c(cc(cc6)C(F)(F)F)F.FC(F)(F)c3cnc(cc3)c4c(cc(cc4)C(F)(F)F)F.F[P-](F)(F)(F)(F)F.n1c(cc(cc1)C(C)(C)C)c2nccc(c2)C(C)(C)C
InChI key
HNVAXJZTSVKZHB-UHFFFAOYSA-N
Application
Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Jack Twilton et al.
Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 912948-500MG | 04061841994879 |
| 912948-50MG | 04061841994886 |