911844
(Me4Phen)NiCl2
powder
Synonym(s):
3,4,7,8-Tetramethyl-1,10-phenanthroline nickel (II) dichloride
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About This Item
Empirical Formula (Hill Notation):
C16H16Cl2N2Ni
CAS Number:
Molecular Weight:
365.91
UNSPSC Code:
12352200
Form:
powder
Product Name
(Me4Phen)NiCl2,
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
231 °C (decomp.)
Application
(Me4Phen)NiCl2 is a Ni catalyst used for a variety of cross-coupling reactions including the cross-electrophile coupling of benzyl alcohols and aryl halides.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Takuya Suga et al.
Organic letters, 20(24), 7846-7850 (2018-12-12)
A nickel-catalyzed cross-electrophile coupling reaction between benzyl alcohols and aryl halides has been developed using a homolytic C-O bond cleavage protocol that has recently been established. The treatment of a benzyl alcohol and aryl halide with a nickel catalyst and
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 911844-1G | 04061841290711 |
| 911844-250MG | 04061841290728 |