804398
[(TMEDA)Ni(o-tolyl)Cl]
95%, powder
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About This Item
Empirical Formula (Hill Notation):
C13H23ClN2Ni
CAS Number:
Molecular Weight:
301.48
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
[(TMEDA)Ni(o-tolyl)Cl], 95%
Quality Level
assay
95%
form
powder
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
SMILES string
CC1=CC=CC=C1[Ni]Cl.CN(C)CCN(C)C
InChI
1S/C7H7.C6H16N2.ClH.Ni/c1-7-5-3-2-4-6-7;1-7(2)5-6-8(3)4;;/h2-5H,1H3;5-6H2,1-4H3;1H;/q;;;+1/p-1
InChI key
NMLMESVZRUMFAE-UHFFFAOYSA-M
Application
Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
Palladium catalysts in transition metal-catalyzed coupling reactions offer diversity, accessibility, and robustness over nickel catalysts.
Related Content
Doyle group focuses on nucleophilic fluorination using PyFluor and nickel catalysis with modular, air-stable nickel precatalyst.
Jason D Shields et al.
Organic letters, 17(9), 2166-2169 (2015-04-18)
The synthesis and catalytic activity of [(TMEDA)Ni(o-tolyl)Cl], an air-stable, crystalline solid, is described. This complex is an effective precatalyst in a variety of nickel-catalyzed transformations. The lability of TMEDA allows a wide variety of ligands to be used, including mono-
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 804398-100MG | 04061833243718 |