907111
2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide
powder or crystals
Synonym(s):
(bpp)NiBr2
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About This Item
Empirical Formula (Hill Notation):
C11H9Br2N5Ni
CAS Number:
Molecular Weight:
429.72
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
Product Name
2,6-bis(N-pyrazolyl)pyridine nickel(II) bromide,
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
SMILES string
[Ni+].[Br-].Br.[n]3(nccc3)c1nc(ccc1)[n]2nccc2
InChI
1S/C11H9N5.2BrH.Ni/c1-4-10(15-8-2-6-12-15)14-11(5-1)16-9-3-7-13-16;;;/h1-9H;2*1H;/q;;;+1/p-1
InChI key
ZVPBBPDZLUQKSN-UHFFFAOYSA-M
Application
Precatalyst for alkyl-alkyl cross-coupling; reductive cross-coupling of styrenyl aziridines, dialkyl ether formation, reductive amination.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Doyle group focuses on nucleophilic fluorination using PyFluor and nickel catalysis with modular, air-stable nickel precatalyst.
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Journal of the American Chemical Society, 140(6), 2292-2300 (2018-01-18)
This report describes a three-component, Ni-catalyzed reductive coupling that enables the convergent synthesis of tertiary benzhydryl amines, which are challenging to access by traditional reductive amination methodologies. The reaction makes use of iminium ions generated in situ from the condensation
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 907111-250MG | 04022536041520 |