913014
[1,3-Bis(diphenylphosphino)propane]dibromonickel(II)
≥95%
Synonym(s):
Ni(dppp)Br2
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About This Item
Empirical Formula (Hill Notation):
C27H26Br2NiP2
CAS Number:
Molecular Weight:
630.94
UNSPSC Code:
12352101
assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Application
[1,3-Bis(diphenylphosphino)propane]dibromonickel(II) is catalyst for:
- Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
- Solid state metathesis polycondensation
- Polymerization of poly(3-alkoxythiophene)s
- Double bond isomerization
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
Felicia Weber et al.
Organic letters, 17(12), 2952-2955 (2015-05-30)
A highly reactive nickel catalyst comprising NiCl2(dppp) or NiCl2(dppe) with zinc powder, ZnI2 and Ph2PH, was applied in the isomerization of terminal alkenes to Z-2-alkenes. The double-bond geometry of the 2-alkene can be controlled via the reaction temperature to yield
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 913014-500MG | 04061841389705 |