911984
(2,2′-Bipyridine)diiodonickel(II)
powder or crystals
Synonym(s):
(bpy)NiI2
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About This Item
Empirical Formula (Hill Notation):
C10H8I2N2Ni
CAS Number:
Molecular Weight:
468.69
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
Product Name
(2,2′-Bipyridine)diiodonickel(II),
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
SMILES string
[Ni]1([NH]2=C(C3=[NH]1C=CC=C3)C=CC=C2)(I)I
InChI key
HXZGEUKJJFSILG-UHFFFAOYSA-L
Application
(2,2′-Bipyridine)diiodonickel(II) is a catalyst for the cross-electrophile coupling of vinyl halides and alkyl halides.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Kirk W Shimkin et al.
Journal of the American Chemical Society, 140(23), 7074-7078 (2018-05-26)
Nickel-catalyzed cross-electrophile couplings have recently emerged as highly effective and practical methods for the formation of C-C bonds. By merging this process with well-established π-π coupling chemistry, a new method for the synthesis of tetrasubstituted alkenes has been developed. The
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 911984-500MG | 04061841389293 |