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Merck
CN

922900

GPhos Pd G6 TES

powder

Synonym(s):

GPhos OAC precatalyst TES

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About This Item

Empirical Formula (Hill Notation):
C47H70BrO4PPdSi
CAS Number:
Molecular Weight:
944.44
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
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Product Name

GPhos Pd G6 TES,

Quality Level

product line

Buchwald precatalyst Generation 6

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

SMILES string

CC(C)c1c(c2c([P](C3CCCCC3)(C4CCCCC4)[Pd](c5ccc(C(OCC[Si](C)(C)C)=O)cc5)Br)c(C)ccc2C)c(C(C)C)ccc1

InChI

1S/C32H47P.C12H17O2Si.BrH.Pd/c1-22(2)28-18-13-19-29(23(3)4)31(28)30-24(5)20-21-25(6)32(30)33(26-14-9-7-10-15-26)27-16-11-8-12-17-27;1-15(2,3)10-9-14-12(13)11-7-5-4-6-8-11;;/h13,18-23,26-27H,7-12,14-17H2,1-6H3;5-8H,9-10H2,1-3H3;1H;

InChI key

TZDQPFRWRQKAKO-UHFFFAOYSA-N

Application

GPhos Pd G6 TES is a sixth generation (G6) Buchwald palladium precatalyst for cross-coupling reactions with demonstrated use for the room temperature coupling of primary amines with aryl halides.

Learn more about G6 Buchwald precatalysts


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.





Global Trade Item Number

SKUGTIN
922900-100MG04065266894929