804177
SnAP 3-Spiro-(2-Pyr) M Reagent
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About This Item
Empirical Formula (Hill Notation):
C23H48N2O3Sn
Molecular Weight:
519.35
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
form
liquid
Quality Level
refractive index
n/D 1.489
density
1.122
functional group
ether
storage temp.
−20°C
SMILES string
CCCC[Sn](CCCC)(COCC1(CN(C(OC(C)(C)C)=O)CC1)N)CCCC
InChI
1S/C11H21N2O3.3C4H9.Sn/c1-10(2,3)16-9(14)13-6-5-11(12,7-13)8-15-4;3*1-3-4-2;/h4-8,12H2,1-3H3;3*1,3-4H2,2H3;
InChI key
JLZWEXDNLRNRBE-UHFFFAOYSA-N
General description
The product is a substituted SnAP [Sn(tin) amino protocol] reagent. SnAP reagents are air and moisture stable.
Application
SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group
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Other Notes
Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
Regulatory Information
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Protocols
SnAP试剂是一种种类不断扩充的试剂，现在可用来方便地合成中等环（6-9元）饱和N-杂环，包括双环和螺环结构。
SnAP Reagents facilitate synthesis of saturated N-heterocycles for diverse structures.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 804177-500MG | 04061833243671 |