900756
SLAP M
≥95%
Synonym(s):
2-((Trimethylsilyl)methoxy)ethan-1-amine
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About This Item
Empirical Formula (Hill Notation):
C6H17NOSi
CAS Number:
Molecular Weight:
147.29
UNSPSC Code:
12352200
assay
≥95%
form
liquid
storage temp.
2-8°C
SMILES string
NCCOC[Si](C)(C)C
Application
When used with aliphatic or aromatic aldehydes, this silicon amine protocol (SLAP) reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Protocols
The expanding class of SLAP reagents provides access to saturated N-heterocycles and aliphatic aldehydes and ketones without additional reagents or the generation of toxic byproducts.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 900756-500MG | 04061833251027 |