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Merck
CN

911151

PS-750-M

greener alternative

powder, solid or chunks

Synonym(s):

FI-750-M

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About This Item

Linear Formula:
(C2H4O)nC18H33NO3
CAS Number:
MDL number:
NACRES:
NA.22
UNSPSC Code:
12352200
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Product Name

PS-750-M,

form

solid, (Powder or Solid or Chunks)

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

storage temp.

−20°C

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase the catalytic efficiency and acts as an environmentally benign and sustainable amphiphile. Find details here.

Application

PS-750-M is a custom surfactant developed in the Handa lab. PS-750-M allows for a variety of reactions, including challenging cross-couplings and monofluorination of indoles, to be conducted in water.


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Micelle-Enabled Palladium Catalysis for Convenient sp2-sp3 Coupling of Nitroalkanes with Aryl Bromides in Water Under Mild Conditions
Brals J, et al.
ACS Catalysis, 10, 7245-7250 (2017)
Lucie Finck et al.
The Journal of organic chemistry, 83(14), 7366-7372 (2018-02-10)
Using micelles of FI-750-M, visible light, photocatalysts, and inexpensive halogenating reagents, such as N-bromosuccinimide and N-chlorosuccinimde, selective oxyhalogenations of alkynes were achieved in water under very mild conditions. No halogenation at the aromatic rings was detected, and control experiments revealed
Pranjal P Bora et al.
ChemSusChem, 12(13), 3037-3042 (2019-03-06)
Highly selective direct monofluorination of indoles and arenes was developed through an approach that allows site-specific solubility of substrate and fluorine source in the micelle. This approach was highly selective for a broad range of substrates with excellent functional group



Global Trade Item Number

SKUGTIN
911151-10G04061841102953
911151-1G04061841102960
911151-25G04061841102977