912646
tBuBrettPhos Pd G6 bromide
powder or crystals
Synonym(s):
tBuBrettPhos OAC precatalyst Br
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About This Item
Empirical Formula (Hill Notation):
C38H53BrF3O2PPd
Molecular Weight:
816.12
UNSPSC Code:
12161600
NACRES:
NA.22
Product Name
tBuBrettPhos Pd G6 bromide,
Quality Level
product line
Buchwald precatalyst Generation 6
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
Application
tBuBrettPhos Pd G6 bromide is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
Learn more about G6 Buchwald precatalysts
Learn more about G6 Buchwald precatalysts
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 912646-1G | 04061841784043 |
| 912646-100MG | 04061841784029 |