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916455

AlPhos Pd G6 OTf

powder

Synonym(s):

AlPhos OAC precatalyst OTf

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About This Item

Empirical Formula (Hill Notation):
C60H71F10O4PPdS
CAS Number:
2097600-18-3
Molecular Weight:
1215.65
UNSPSC Code:
12352100
NACRES:
NA.22
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Product Name

AlPhos Pd G6 OTf,

product line

Buchwald precatalyst Generation 6

Quality Level

100

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

SMILES string

[Pd+]c%10ccc(cc%10)C(F)(F)F.Fc1c(c(c(c(c1CCCC)F)F)c2c(c(c(cc2C(C)C)C(C)C)c3c(c(ccc3)OC)P([C@]87C[C@H]9C[C@@H](C8)C[C@@H](C7)C9)[C@]54C[C@H]6C[C@@H](C5)C[C@@H](C4)C6)C(C)C)F.FC(F)(F)[S](=O)(=O)[O-]

InChI key

QJLVEPMTRMVTFU-HZBKTHAQSA-M

Application

AlPhos Pd G6 OTf is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

Other Notes

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Articles

Buchwald G6 Precatalysts: Oxidative Addition Complexes

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

Global Trade Item Number

SKUGTIN
916455-100MG04061842449286